臭氧氧化-循环喷淋法处理钨钼选矿废水

采用臭氧氧化-循环喷淋法去除钨钼选矿废水中COD,研究了pH值、臭氧流量、循环频率对COD去除效果的影响。结果表明: 废水COD去除率随pH值、臭氧流量、循环频率增大而增加,在pH值为10、臭氧流量3.0 L/min、循环频率4.0次/min条件下,氧化120 min后废水COD含量由131 mg/L降至11.5 mg/L,COD去除率达91.2%,满足《污水综合排放标准》(GB 8978-1996)一级标准。与O₂、NaClO处理废水COD的对比试验结果表明,循环喷淋法结合O₃表现出较好的COD去除效果。     

基于多元神经网络融合的分布式资源空间文本分类研究

针对实体产业对科技资源的服务需求,以服务效应作为资源文本分类标准,提出一种基于多元神经网络融合的分布式资源空间文本分类模型。设计了包含词嵌入层、卷积层、双向门控循环单元层、注意力机制层和softmax层的多元神经网络通路;在此基础上采用基于需求—效应—资源分类策略,完成了从定性科技资源需求到定量资源服务效应求解,再到定性科技资源输出的映射变换,重点解决了分布式科技资源局部和全局语义特征形式多样、文本长距离依赖特征显著、重要资源信息难以准确识别的问题,进而从分布式科技资源空间中快速准确地获取效应知识,提升实体产业产品研发效率和创新能力;通过万方专利科技资源数据集验证了所提方法的可行性和有效性,为更加全面地挖掘资源文本特征和按需服务实体产业提供了一种新的思路和手段。     

Cobalt ferrite nanoparticles prepared by microwave hydrothermal synthesis and adsorption efficiency for organic dyes: Isotherms,thermodynamics and kinetic studies

Magnetic nanoferrites (MFe₂O₄, M = Co, Ni) were successfully synthesised through microwave-hydrothermal route, characterised and used for adsorption of Eriochrome Black T (EBT) and Bromophenol Blue (BRB) dyes from their aqueous solution. The powder XRD patterns confirmed the formation of cubic spinel structure for both the ferrites. Under identical conditions, the adsorption efficiency of CoFe₂O₄ was found relatively higher than the corresponding NiFe₂O_4. Further characterisations revealed that CoFe₂O₄ sample was nearly spherical in size (8–9 nm) with narrow size distribution. The sample showed superparamagnetic behaviour with saturation magnetization (M_s) value (66.4 emu/g). BET surface area calculated for the synthesized cobalt ferrite as 70.9 m²/g. Batch adsorption experiments as a function of initial dye concentration, pH, contact time and adsorbent dose showed the adsorption of dyes depends on pH. Equilibrium adsorption data were well explained by both Langmuir and Freundlich isotherm models. The maximum monolayer adsorption capacities (Q_o) were found to be 82.6 and 25.6 mg/g for EBT and BRB dyes, respectively. Kinetics of the adsorption was best described by pseudo-second-order model. Various thermodynamic parameters such as ΔG, ΔH and ΔS derived from adsorption data over the temperature range 20–50 °C, accounted for a favourable, spontaneous, endothermic physisorption process. The materials showed potential for repeated use without significant decrease in adsorption capacity after proper regeneration.     

小尺度交通信号灯的检测与状态识别

交通信号灯识别包括检测和状态识别，在智能交通系统中发挥重要作用。基于YOLOv3算法提出了一种交通信号灯检测与状态识别模型。针对交通信号灯相较于交通场景中其他目标具有尺度小的特性进行了算法的设计：降低骨干网络的下采样倍率以增加小尺度目标的特征描述能力；通过增大特征图的尺度来改进多尺度特征融合；引入广义交并比作为检测任务的损失函数来改进目标边界框的回归效果。同时，根据交通信号灯本身的特性，使用颜色和形状约束的方法对信号灯进行状态识别和类别验证。最后在公开的Bosch交通信号灯数据集上和实际的城区道路进行了实验验证。实验结果表明，所提出的算法能够提升交通信号灯识别的精度和召回率，识别准确率可以达到90%左右。     

Practices,projects and portfolios: Current research trends and new directions

Project portfolio management (PPM) bridges strategy and project management. Traditional research in PPM has primarily investigated the rational, top-down and structural aspects of strategizing. By doing so, it has failed to focus on the underlying practices that are triggered by the strategy and how these practices frame strategy implementation. Practice-based research provides a methodological lens to explore the reality of strategic enactment through the project portfolio. Practice-based perspectives are under-represented in PPM research; therefore the aim of this paper is to provide an agenda for further practice-based research in PPM. Central to this agenda is a concern with various aspects of practice, including its discursivity, representation, dynamic capabilities, leadership and materiality.     

β-环糊精修饰Ni/SFCC强化C9石油树脂催化加氢性能

以废弃的流化催化裂化催化剂（简称SFCC）为载体、β-环糊精为金属络合剂、硝酸镍为镍源，采用湿法浸渍法制备β-环糊精修饰的Ni/SFCC催化剂（简称Ni/SFCC-CD催化剂），考察其对C9石油树脂的催化加氢性能。通过BET比表面积测试、H2程序升温还原、X射线光电子能谱等手段对催化剂的物相结构进行表征，研究β-环糊精的作用机理及其对催化剂加氢性能的影响。研究结果表明：在反应温度为260 ℃、反应压力为7 MPa、反应时间为2.0 h的最优条件下，采用Ni/SFCC-CD催化C9石油树脂加氢，可制得溴值为1.45 gBr/（100 g）、色号（加纳德）小于1的水白色氢化C9石油树脂，催化剂循环使用4次后仍保持良好活性；β-环糊精的作用机理是：β-环糊精与硝酸镍产生络合作用，抑制硝酸镍的分解、控制NiO的结晶过程和增强活性组分Ni与载体之间的相互作用力，从而提高了Ni/SFCC-CD的催化活性和稳定性。     

耦合效应下压力型锚索锚固机理的近似理论分析

为了更加精确地研究压力型锚索的锚固机理,基于锚索预应力与岩土体蠕变的耦合效应推导了锚索预应力方程。在此基础上根据Mindlin问题解,推导了耦合效应作用下锚索砂浆体的压应力和剪应力近似解,并考虑锚索预应力与岩土体蠕变之间的耦合效应进行了案例分析。研究结果表明:锚索预应力和砂浆体受到的应力峰值均按反幂函数随时间逐渐衰减并稳定;承压板的长宽比与压应力峰值之间存在正相关关系,与剪应力峰值之间存在负相关关系;岩土体的泊松比与应力峰值之间存在正相关关系。该成果丰富了压力型锚索锚固机理的理论研究,可为边坡锚固设计提供一定的理论依据。     

Sequence-Dependent Nanofiber Structures of Phenylalanine and Isoleucine Tripeptides

The molecular design of short peptides to achieve a tailor-made functional architecture has attracted attention during the past decade but remains challenging as a result of insufficient understanding of the relationship between peptide sequence and assembled supramolecular structures. We report a hybrid-resolution model to computationally explore the sequence–structure relationship of self-assembly for tripeptides containing only phenylalanine and isoleucine. We found that all these tripeptides have a tendency to assemble into nanofibers composed of laterally associated filaments. Molecular arrangements within the assemblies are diverse and vary depending on the sequences. This structural diversity originates from (1) distinct conformations of peptide building blocks that lead to different surface geometries of the filaments and (2) unique sidechain arrangements at the filament interfaces for each sequence. Many conformations are available for tripeptides in solution, but only an extended β-strand and another resembling a right-handed turn are observed in assemblies. It was found that the sequence dependence of these conformations and the packing of resulting filaments are determined by multiple competing noncovalent forces, with hydrophobic interactions involving Phe being particularly important. The sequence pattern for each type of assembly conformation and packing has been identified. These results highlight the importance of the interplay between conformation, molecular packing, and sequences for determining detailed nanostructures of peptides and provide a detailed insight to support a more precise design of peptide-based nanomaterials.     

Effects of Synthesis Conditions on the Formation of Si-Substituted Alpha Tricalcium Phosphates

Powders of α-TCP containing various amounts of silicon were synthesized by two different methods: Wet chemical precipitation and solid-state synthesis. The obtained powders were then physico–chemically studied using different methods: Scanning and transmission electron microscopy (TEM and SEM), energy-dispersive X-ray spectroscopy (EDS), powder X-ray diffractometry (PXRD), infrared and Raman spectroscopies (FT-IR and R), and solid-state nuclear magnetic resonance (ssNMR). The study showed that the method of synthesis affects the morphology of the obtained particles, the homogeneity of crystalline phase and the efficiency of Si substitution. Solid-state synthesis leads to particles with a low tendency to agglomerate compared to the precipitation method. However, the powders obtained by the solid-state method are less homogeneous and contain a significant amount of other crystalline phase, silicocarnotite (up to 7.33%). Moreover, the microcrystals from this method are more disordered. This might be caused by more efficient substitution of silicate ions: The silicon content of the samples obtained by the solid-state method is almost equal to the nominal values.     

Shape optimization of bi-directional flow passage components based on a genetic algorithm and computational fluid dynamics

The inlet/outlet is an important part of a water conveyance system in a pumped storage power station (PSPS). Its hydraulic characteristics are directly related to the operation and economic benefit of the PSPS. Frequent changes between inflow and outflow operations pose significant challenges in the design of the inlet/outlet diffusion segment shape. In this study, an effective optimization method, including three-dimensional parametric modelling, computational fluid dynamics and a genetic algorithm, is introduced and coupled to the design of the diffusion segment shape. The hydraulic characteristics of bi-directional flow, including the head loss, velocity uneven distribution and uneven discharge distribution, are selected as the objective function in the optimization method. Using this method, the recommended shape of the inlet/outlet is studied and its hydraulic characteristics are discussed. The results indicate that the optimized inlet/outlet has better performance.